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Atomic: M.A.C. | Reference
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Reactions of Polonium
Reactions with water
Polonium does not react with water.
Reactions with air
Polonium burns in air to form polonium(IV) dioxide.
  Po(s) + 2O2(g)PO2(s)
Reactions with halogens
Under controlled conditions polonium will react with chlorine, bromine and iodine to form tetrahalides.
  Po(s) + 2Cl2(g)PoCl4(s)
  Po(s) + 2Br2(g)PoBr4(s)
  Po(s) + 2I2(g)PoI4(s)
Reactions with acids
Polonium will dissolve in concentrated hydrochloric acid, sulphuric acid and nitric acid, to form solutions containing Po(II).